As the eventual goal is to compare the homotopy theory of spaces with the homotopy theory of cdga's, it is natural to investigate an analogue of homotopy groups in the category of cdga's. In topology we can only define homotopy groups on pointed spaces, dually we will consider augmented cdga's in this section.
Let $h: A \to\Lambda(t, dt)\tensor X$ be a homotopy. We will, just as in \LemmaRef{cdga-homotopy-homology}, prove that the maps $HQ(d_0)$ and $HQ(d_1)$ are equal, then it follows that $HQ(f)= HQ(d_1 h)= HQ(d_0 h)= HQ(g)$.
Now $Q(\Lambda(t, dt))= D(0)$ and hence it is acyclic, so when we pass to homology, this term vanishes. In other words both maps ${d_i}_\ast : H(D(0))\oplus H(Q(A))\to H(Q(A))$ are the identity maps on $H(Q(A))$.
Consider the augmented cdga $V(n)= S(n)\oplus\k$, with trivial multiplication and where the term $\k$ is used for the unit and augmentation. This augmented cdga can be thought of as a specific model of the sphere. In particular the homotopy groups can be expressed as follows.
\Lemma{cdga-dual-homotopy-groups}{
There is a natural bijection for any augmented cdga $A$
$$[A, V(n)]\tot{\iso}\Hom_\k(\pi^n(A), \k). $$
}
\Proof{
Note that $Q(V(n))$ in degree $n$ is just $\k$ and $0$ in the other degrees, so its homotopy groups consists of a single $\k$ in degree $n$. This establishes the map:
Now by \LemmaRef{cdga-homotopic-maps-equal-pin} we get a map from the set of homotopy classes $[A, V(n)]$ instead of the $\Hom$-set. It remains to prove that the map is an isomorphism. Surjectivity follows easily. Given a map $f: \pi^n(A)\to\k$, we can extend this to $A \to V(n)$ because the multiplication on $V(n)$ is trivial.
For injectivity suppose $\phi, \psi: A \to V(n)$ be two maps such that $\pi^n(\phi)=\pi^n(\psi)$. We will first define a chain homotopy $D: A^\ast\to V(n)^{\ast-1}$, for this we only need to specify the map $D^n: A^{n+1}\to V(n)^n =\Q$. Decompose the vector space $A^{n+1}$ as $A^{n+1}=\im d \oplus V$ for some $V$. Now set $D^n(v)=0$ for all $v \in V$ and $D^n(db)=\phi(b)-\psi(b)$. We should check that $D$ is well defined. Note that for cycles we get $\phi(c)=\psi(c)$, as $H(Q(\phi))= H(Q(\psi))$. So if $db = dc$, then we get $D(db)=\phi(b)-\psi(b)=\phi(c)-\psi(c)= D(dc)$, i.e. $D$ is well defined. We can now define a map of augmented cdga's:
\begin{align*}
h : X &\to\Lambda(t, dt) \overline{\tensor} V(n) \\
x &\mapsto dt \tensor D(x) + 1 \tensor\phi(x) - t \tensor\phi(x) + t \tensor\psi(x)
\end{align*}
This map commutes with the differential by the definition of $D$. Now we see that $d_0 h =\psi$ and $d_1 h =\phi$. Hence the two maps represent the same class, and we have proven the injectivity.
From now on the dual of a vector space will be denoted as $V^\ast=\Hom_\k(V, \k)$. So the above lemma states that there is a bijection $[A, V(n)]\iso\pi^n(A)^\ast$.
In topology we know that a fibration induces a long exact sequence of homotopy groups. In the case of cdga's a similar long exact sequence for a cofibration will exist.
\Lemma{long-exact-cdga-homotopy}{
Given a pushout square of augmented cdga's
\[\xymatrix{
A \ar[d]^-f \arcof[r]^-g \xypo& C \ar[d]^-i \\
B \ar[r]^-j & P
}\]
where $g$ is a cofibration. There is a natural long exact sequence
First note that $j$ is also a cofibration. By \LemmaRef{Q-preserves-cofibs} the maps $Qg$ and $Qj$ are injective in positive degrees. By applying $Q$ we get two exact sequence (in positive degrees) as shown in the following diagram. By the fact that $Q$ preserves pushouts (\CorollaryRef{Q-preserves-pushouts}) the cokernels coincide.